To obtain the XML file to use to upload/edit in WebMatrix, log into your Plesk account control panel, then:
Go to "Websites & Domains"
Scroll down and click "Show Advanced Operations"
Click "Web Deploy Publishing Settings"
You will then be provided with your .publishsettings file you can submit in WebMatrix.
You can download WebMatrix for free: http://www.microsoft.com/web/webmatrix/
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