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For detailed instructions for publishing using Web Deploy: http://msdn.microsoft.com/en-us/library/dd465337.aspx
It's because 4.5 is simply an update of 4.0, therefore in Plesk the version appears as 4.0...
On our Windows Hosting plans, your website should be uploaded to your httpdocs folder.
You can download WebMatrix for free: http://www.microsoft.com/web/webmatrix/
If you have multiple Windows hosting plans with us, when logging into Plesk, you need to login...
To obtain the XML file to use to upload/edit in WebMatrix, log into your Plesk account...